Hydroisomerization of n-Heptane in a Fixed-Bed Reactor Using a Synthesized Bimetallic Type-HY Zeolite Catalyst

نویسندگان

چکیده

The synthesis of NaY-zeolite was performed hydrothermally. preparation the bifunctional catalysts achieved by loading NH4Y-zeolite with a cheap Zr metal, as second tiny amounts Pt to compose Pt-Zr/Y-zeolite catalyst. Different characterization methods (i.e., XRD, SEM, EDX, BET, and AFM) were used investigate catalyst properties. catalytic performance studied performing hydroisomerization n-heptane in gas phase at temperature 275°C atmospheric pressure fixed-bed reactor. GC-FID results products confirmed positive role enhancing features, reflected increase isomerized decrease unwanted by-products. Incorporating 1.0wt%Zr 1.0wt% significantly improved activity selectivity increased yield branched alkanes. This because addition zirconium provided an extraordinary Lewis acidity zeolite-framework structure simultaneously took advantage electronic properties metals enhance its novel features. reduced amount metal halved cost In addition, bimetallic (HY-zeolite loaded 1wt%Pt & 1wt%Zr) values 74.2, 78.8, 58.5mol% for conversion, selectivity, yield, respectively. conversion level close 2wt% Pt/HY-zeolite catalyst, while not decreased from that Zr/HY-zeolite reaching isomers catalysts.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Determination of the Deactivation Model of Iron-potassium/γ-Al2O3 Catalyst in a Fixed Bed Reactor

Catalyst activity and performance are the most important factors for selecting a catalyst in different processes. The Fischer-Tropsch synthesis is a very important synthesis that extensive action has been taken place to increase the activity of its catalysts in the recent century. Deactivation of the catalysts of the process is influenced by many factors, among which coking and sintering have c...

متن کامل

Investigating the Batch and Continuous Transesterification of Linseed Oil by Using a Alkaline Heterogeneous Catalyst in a Packed Bed Reactor

Both the continuous and batch transesterification of linseed oil were examined in order to maximize the fatty acid methyl esters (FAME) yield. The continuous process was conducted in a packed bed reactor using calcium oxide as a heterogeneous catalyst. In addition, the impact of two variables, namely the molar ratio of methanol to oil and the flow rate (ml/min), on the FAME yield were stu...

متن کامل

Pressurised pyrolysis of Miscanthus using a fixed bed reactor.

Miscanthus x giganteus was pyrolysed, in a fixed bed reactor in a constant flow of dinitrogen gas, at a rate of 13°C/min from ambient to 550°C, then held for 25 min at this temperature. The pressures employed ranged from atmospheric to 26 bar. The major compounds identified in the bio-oil were water, phenol, and phenol derivatives. The water contents impact on the usefulness of the bio-oil as a...

متن کامل

Determination of the Product Selectivity Model from the Fischer Tropsch Synthesis in a Fixed Bed Reactor

The Fischer-Tropsch synthesis is a catalytic process that can produce a fuel similar to fossil fuels by using primary sources such as agricultural waste and carbon sources that can convert into synthesis gas by superheated steam. All fuel derivatives can be supplied through the Fischer-Tropsch reaction. The synthesis produces a variety of hydrocarbons via parallel and sequential reactions. Howe...

متن کامل

Control of a Fluidized Bed Polyethylene Reactor

In present paper, dynamic behavior and control of a fluidized bed reactor for polyethylene production has been considered. A double active sites model for Ziegler-Natta catalysts is used for simulation of polymerization reaction. Hydrodynamic behavior of the bed is modeled using a two phase model including bubble and emulsion phases in which bubble phase has plug flow pattern with different...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Ma?allat? al-handasat? wa-al-tikn?l??iy?

سال: 2022

ISSN: ['1681-6900', '2412-0758']

DOI: https://doi.org/10.30684/etj.2022.132491.1124